I have skin that is acne-prone and this product has not made me break out at all. It works beautifully on my skin, mattes out shine and makes my make-up last at least 8 hours. I find it non-irritating. Try it on in-stores!
If you don't do these things already, I highly recommend thoroughly (but gently) removing all traces of make-up before bed (or, even better, much earlier in the day), washing make-brushes every week and keeping your fingers/hair off your face.

I think it's an error on the website because this is definitely a talc-free product. It seems confusing, but I double checked my most recently purchased pot of this powder (from a few weeks ago) and no talc listed. If it helps, I got it specifically because it was talc free. :)